The synthesis, characterisation and electronic structure of N-heterocyclic carbene adducts of P(I) cations

The synthesis, characterisation and electronic structure of N-heterocyclic carbene adducts of P(I) cations

Two different syntheses of N-heterocyclic carbene complexes of P(I) cations are presented; the structural features of these phosphamethine cyanine salts, in conjunction with the results of computational investigations, provide insight into the nature of the bonding of these heavy allene analogues.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-04 (15), p.1965-1967
Hauptverfasser: Ellis, Bobby D, Dyker, C Adam, Decken, Andreas, Macdonald, Charles L B
Format: Artikel
Sprache:eng
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Zusammenfassung:Two different syntheses of N-heterocyclic carbene complexes of P(I) cations are presented; the structural features of these phosphamethine cyanine salts, in conjunction with the results of computational investigations, provide insight into the nature of the bonding of these heavy allene analogues.
ISSN:1359-7345
DOI:10.1039/b500692a