Modular Diamino- and Dioxophosphine Oxides and Chlorides as Ligands for Transition-Metal-Catalyzed CC and CN Couplings with Aryl Chlorides

Modular Diamino- and Dioxophosphine Oxides and Chlorides as Ligands for Transition-Metal-Catalyzed CC and CN Couplings with Aryl Chlorides

Air‐stable diamino‐ and dioxophosphine oxides were used as ligands in palladium‐catalyzed Suzuki reactions of aryl chlorides. Additionally, a diaminophosphine chloride was applied to palladium‐ and nickel‐catalyzed CC and CN bond‐forming reactions.

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Veröffentlicht in:Angewandte Chemie International Edition 2005-04, Vol.44 (16), p.2444-2447
Hauptverfasser: Ackermann, Lutz, Born, Robert
Format: Artikel
Sprache:eng
Schlagworte:
cross-coupling
nickel
P ligands
palladium
phosphorus trichloride
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Zusammenfassung:Air‐stable diamino‐ and dioxophosphine oxides were used as ligands in palladium‐catalyzed Suzuki reactions of aryl chlorides. Additionally, a diaminophosphine chloride was applied to palladium‐ and nickel‐catalyzed CC and CN bond‐forming reactions.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200462371