Fullerene−Porphyrin Constructs

Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host−guest complexes, as well as ordered arrays of interleaved porphyrins and fullerenes. The fullerene−porphyrin interaction underlies successful chroma...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Accounts of chemical research 2005-04, Vol.38 (4), p.235-242
Hauptverfasser: Boyd, Peter D. W, Reed, Christopher A
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host−guest complexes, as well as ordered arrays of interleaved porphyrins and fullerenes. The fullerene−porphyrin interaction underlies successful chromatographic separations of fullerenes, and there are promising applications in the areas of porous framework solids and photovoltaic devices.
ISSN:0001-4842
1520-4898
DOI:10.1021/ar040168f