Collisions of DCl with Pure and Salty Glycerol:  Enhancement of Interfacial D → H Exchange by Dissolved NaI

The fate of DCl molecules striking pure glycerol and a 2.6 M NaI−glycerol solution is investigated using scattering, uptake, and residence time measurements. We find that dissolved Na+ and I- ions alter every gas−liquid pathway from the moment of contact of DCl with the surface to its eventual emerg...

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Veröffentlicht in:The journal of physical chemistry. B 2006-03, Vol.110 (10), p.4881-4891
Hauptverfasser: Muenter, Annabel H, DeZwaan, Jennifer L, Nathanson, Gilbert M
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Sprache:eng
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