Variation in crystallization conditions allows the isolation of trimeric as well as dimeric and monomeric forms of [(alkyl isocyanide)4RhI]

Variation in crystallization conditions allows the isolation of trimeric as well as dimeric and monomeric forms of [(alkyl isocyanide)4RhI]

Trimeric green [(i-PrNC)12Rh(I)3]Cl3.4.5H2O, monomeric [(C6H11NC)4Rh(I)](BPh4) and [(i-PrNC)4Rh(I)](BPh4) (both yellow), and red, dimeric [(C6H11NC)8Rh(I)2]Cl2.0.5C6H6.2H2O have been crystallized.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-01 (10), p.1130-1132
Hauptverfasser: Tran, Ngon T, Stork, Jay R, Pham, David, Olmstead, Marilyn M, Fettinger, James C, Balch, Alan L
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Trimeric green [(i-PrNC)12Rh(I)3]Cl3.4.5H2O, monomeric [(C6H11NC)4Rh(I)](BPh4) and [(i-PrNC)4Rh(I)](BPh4) (both yellow), and red, dimeric [(C6H11NC)8Rh(I)2]Cl2.0.5C6H6.2H2O have been crystallized.
ISSN:1359-7345
1364-548X
DOI:10.1039/b513700d