Highly Enantioselective Hydrovinylation of α-Alkyl Vinylarenes. An Approach to the Construction of All-Carbon Quaternary Stereocenters

The highly enantioselective hydrovinylation of α-alkyl vinylarenes was realized by using nickel complexes of chiral spiro phosphoramidite ligands. The method provided a new approach to the construction of chiral all-carbon quaternary centers.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2006-03, Vol.128 (9), p.2780-2781
Hauptverfasser:	Shi, Wen-Jian, Zhang, Qi, Xie, Jian-Hua, Zhu, Shou-Fei, Hou, Guo-Hua, Zhou, Qi-Lin
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactivity Chemistry Exact sciences and technology Hydrocarbons, Aromatic - chemical synthesis Hydrocarbons, Aromatic - chemistry Organic chemistry Organophosphorus Compounds - chemistry Reactivity and mechanisms Stereoisomerism Vinyl Compounds - chemical synthesis Vinyl Compounds - chemistry
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Beschreibung
Zusammenfassung:	The highly enantioselective hydrovinylation of α-alkyl vinylarenes was realized by using nickel complexes of chiral spiro phosphoramidite ligands. The method provided a new approach to the construction of chiral all-carbon quaternary centers.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja057654y