Tris(1,10-phenanthroline)copper(II) di-μ-iodo-bis­(diiodo­mercurate) dimethyl sulfoxide monohydrate

Tris(1,10-phenanthroline)copper(II) di-μ-iodo-bis­(diiodo­mercurate) dimethyl sulfoxide monohydrate

In the cationic complex present in the title compound, [Cu(C12H8N2)3][Hg2I6]·C2H6OS·H2O, the copper(II) center adopts a highly distorted octa­hedral geometry, ligated by the six N atoms of three 1,10‐phenanthroline ligands. The structure includes an iodide‐bridged dimeric mercurate anion for neutral...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2006-02, Vol.62 (2), p.m51-m53
Hauptverfasser: Oh, Myeong-Jin, Lee, Yong-Min, Lee, Seung Jae, Kang, Sung Kwon, Choi, Sung-Nak
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Zusammenfassung:In the cationic complex present in the title compound, [Cu(C12H8N2)3][Hg2I6]·C2H6OS·H2O, the copper(II) center adopts a highly distorted octa­hedral geometry, ligated by the six N atoms of three 1,10‐phenanthroline ligands. The structure includes an iodide‐bridged dimeric mercurate anion for neutrality and uncoordinated dimethyl sulfoxide and water mol­ecules.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270105043088