Heterodinuclear Cu−Tb Single-Molecule Magnet

Heterodinuclear Cu−Tb Single-Molecule Magnet

A strictly heterodinuclear Cu−Tb complex [LCu(O2COMe)Tb(thd)2] made with a Schiff base L, thd, and monomethylcarbonate ligands [L2- = N,N‘-2,2-dimethylpropylenedi(3-methoxysalicylideneiminato); thd = tetramethylheptanedionato] behaves like a single-molecule magnet. The monomethylcarbonate ligand, wh...

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Veröffentlicht in:Inorganic chemistry 2006-01, Vol.45 (1), p.5-7
Hauptverfasser: Costes, Jean-Pierre, Dahan, Françoise, Wernsdorfer, Wolfgang
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Dahan, Françoise
Wernsdorfer, Wolfgang
description A strictly heterodinuclear Cu−Tb complex [LCu(O2COMe)Tb(thd)2] made with a Schiff base L, thd, and monomethylcarbonate ligands [L2- = N,N‘-2,2-dimethylpropylenedi(3-methoxysalicylideneiminato); thd = tetramethylheptanedionato] behaves like a single-molecule magnet. The monomethylcarbonate ligand, which appears during the reaction pathway, bridges the Cu and Tb ions.
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