Heterodinuclear Cu−Tb Single-Molecule Magnet
A strictly heterodinuclear Cu−Tb complex [LCu(O2COMe)Tb(thd)2] made with a Schiff base L, thd, and monomethylcarbonate ligands [L2- = N,N‘-2,2-dimethylpropylenedi(3-methoxysalicylideneiminato); thd = tetramethylheptanedionato] behaves like a single-molecule magnet. The monomethylcarbonate ligand, wh...
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| Veröffentlicht in: | Inorganic chemistry 2006-01, Vol.45 (1), p.5-7 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A strictly heterodinuclear Cu−Tb complex [LCu(O2COMe)Tb(thd)2] made with a Schiff base L, thd, and monomethylcarbonate ligands [L2- = N,N‘-2,2-dimethylpropylenedi(3-methoxysalicylideneiminato); thd = tetramethylheptanedionato] behaves like a single-molecule magnet. The monomethylcarbonate ligand, which appears during the reaction pathway, bridges the Cu and Tb ions. |
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| ISSN: | 0020-1669 1520-510X |
| DOI: | 10.1021/ic050563h |