Soluble and Highly Conductive Ionomer for High-Performance Hydroxide Exchange Membrane Fuel Cells

Easy cell: The new polymeric ionomer TPQPOH with a tris(2,4,6‐trimethoxyphenyl)phosphonium unit has excellent solubility in some low‐boiling‐point water‐soluble solvents, high ionic conductivity, and outstanding alkaline stability. A hydroxide exchange membrane fuel cell containing this ionomer exhi...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-01, Vol.48 (35), p.6499-6502
Hauptverfasser: Gu, Shuang, Cai, Rui, Luo, Ting, Chen, Zhongwei, Sun, Minwei, Liu, Yan, He, Gaohong, Yan, Yushan
Format: Artikel
Sprache:eng
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Zusammenfassung:Easy cell: The new polymeric ionomer TPQPOH with a tris(2,4,6‐trimethoxyphenyl)phosphonium unit has excellent solubility in some low‐boiling‐point water‐soluble solvents, high ionic conductivity, and outstanding alkaline stability. A hydroxide exchange membrane fuel cell containing this ionomer exhibits increased peak power density and reduced internal resistance.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200806299