Dynamics of internal stresses and scaling of strain recovery in an aging colloidal gel

We monitor the relaxation of internal stresses in a fractal colloidal gel on cessation of flow and find a weak power-law decay, sigmai approximately t(-alpha) over five decades of time where alpha approximately 0.07. The system exhibits physical aging of the elastic modulus, G' approximately tb...

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Veröffentlicht in:Physical review. E, Statistical, nonlinear, and soft matter physics Statistical, nonlinear, and soft matter physics, 2009-07, Vol.80 (1 Pt 1), p.010404-010404, Article 010404
Hauptverfasser: Negi, Ajay Singh, Osuji, Chinedum O
Format: Artikel
Sprache:eng
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Zusammenfassung:We monitor the relaxation of internal stresses in a fractal colloidal gel on cessation of flow and find a weak power-law decay, sigmai approximately t(-alpha) over five decades of time where alpha approximately 0.07. The system exhibits physical aging of the elastic modulus, G' approximately tbeta, with beta approximately alpha . Imposition of zero stress after waiting time tw results in strain recovery as the system relaxes without constraint. Remarkably, recoveries at different tw can be shifted to construct a master curve where data are scaled vertically by 1/sigmai(tw) and plotted horizontally as (t-tw)/twmu, where mu is approximately 1.25, indicative of a superaging response.
ISSN:1539-3755
1550-2376
DOI:10.1103/physreve.80.010404