High sensitivity nuclear magnetic resonance probe for anvil cell pressure experiments

While the highest pressures can be achieved with diamond anvil cells, limited sample size and anvil geometry have hampered their application in nuclear magnetic resonance (NMR) experiments due to weak signal-to-noise. Here we report a new probe design that is based on having the resonant radio frequ...

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Veröffentlicht in:Review of scientific instruments 2009-07, Vol.80 (7), p.073905-073905-4
Hauptverfasser: Haase, Jürgen, Goh, Swee K., Meissner, Thomas, Alireza, Patricia L., Rybicki, Damian
Format: Artikel
Sprache:eng
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Zusammenfassung:While the highest pressures can be achieved with diamond anvil cells, limited sample size and anvil geometry have hampered their application in nuclear magnetic resonance (NMR) experiments due to weak signal-to-noise. Here we report a new probe design that is based on having the resonant radio frequency coil that encloses the sample within the anvil cell inside the gasket hole. This increases the filling factor tremendously and results in greatly enhanced NMR sensitivity. The setup is described together with room temperature Na and Al NMR experiments.
ISSN:0034-6748
1089-7623
DOI:10.1063/1.3183504