Copper(I) Cuboctahedral Coordination Cages: Host–Guest Dependent Redox Activity

Copper(I) Cuboctahedral Coordination Cages: Host–Guest Dependent Redox Activity

Redox‐active cage: Cu+ coordination cages were assembled from a triangular benzimidazole‐based ligand. The cages have cuboctahedral shaped cavities and their redox activity can be tuned by the guest anions.

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Veröffentlicht in:Angewandte Chemie International Edition 2009-01, Vol.48 (33), p.6156-6159
Hauptverfasser: He, Qi‐Ting, Li, Xiang‐Ping, Liu, Yu, Yu, Zhi‐Quan, Wang, Wei, Su, Cheng‐Yong
Format: Artikel
Sprache:eng
Schlagworte:
cage compounds
copper
host–guest systems
redox activity
self‐assembly
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Beschreibung
Zusammenfassung:Redox‐active cage: Cu+ coordination cages were assembled from a triangular benzimidazole‐based ligand. The cages have cuboctahedral shaped cavities and their redox activity can be tuned by the guest anions.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200902276