Tuning of spin crossover equilibrium in catecholatoiron(III) complexes by supporting ligands

Tuning of spin crossover equilibrium in catecholatoiron(III) complexes by supporting ligands

Introduction of electron-withdrawing groups on co-ligands effectively raises the spin crossover temperature of catecholatoiron(III) complexes and induces a significant amount of the low spin species in solution even at around room temperature.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-04 (13), p.1758-1760
Hauptverfasser: Hitomi, Yutaka, Higuchi, Masakazu, Minami, Hisataka, Tanaka, Tsunehiro, Funabiki, Takuzo
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Introduction of electron-withdrawing groups on co-ligands effectively raises the spin crossover temperature of catecholatoiron(III) complexes and induces a significant amount of the low spin species in solution even at around room temperature.
ISSN:1359-7345
1364-548X
DOI:10.1039/b418678h