Conjugate Additions of Nitroalkanes to Electron-Poor Alkenes:  Recent Results

Conjugate Additions of Nitroalkanes to Electron-Poor Alkenes:  Recent Results

Nitroalkanes are a convenient source of stabilized carbanions that react with electron-poor alkenes giving the corresponding 1,4-adducts with high regioselectivity. The addition process is usually realized in basic media that strongly affects the selectivity and efficiency achievable in carbon-carbo...

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Veröffentlicht in:Chemical reviews 2005-03, Vol.105 (3), p.933-972
Hauptverfasser: Ballini, Roberto, Bosica, Giovanna, Fiorini, Dennis, Palmieri, Alessandro, Petrini, Marino
Format: Artikel
Sprache:eng
Schlagworte:
Alkanes - chemical synthesis
Alkenes - chemical synthesis
Carbon
Catalysis
Chemical bonds
Chemical reactions
Chemistry
Electrons
Indicators and Reagents
Models, Chemical
Molecular Structure
Nitro Compounds - chemistry
Stereoisomerism
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Beschreibung
Zusammenfassung:Nitroalkanes are a convenient source of stabilized carbanions that react with electron-poor alkenes giving the corresponding 1,4-adducts with high regioselectivity. The addition process is usually realized in basic media that strongly affects the selectivity and efficiency achievable in carbon-carbon formation.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr040602r