Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-03 (10), p.1318-1320
Hauptverfasser: Teo, Yong-Chua, Tan, Kui-Thong, Loh, Teck-Peng
Format: Artikel
Sprache:eng
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Zusammenfassung:A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).
ISSN:1359-7345
1364-548X
DOI:10.1039/b412736f