Cleaner Continuous Photo-Oxidation Using Singlet Oxygen in Supercritical Carbon Dioxide

Cleaner Continuous Photo-Oxidation Using Singlet Oxygen in Supercritical Carbon Dioxide

High pressure under the spotlight: A new milliliter-scale reactor is developed for using supercritical CO₂ to perform continuous photo-oxidation reactions. Changing from a traditional microliter-scale batch reaction to 8 hours of reaction using the new reactor gives a 3000-fold scale-up of the oxida...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2009-01, Vol.48 (29), p.5322-5325
Hauptverfasser: Bourne, Richard A, Han, Xue, Poliakoff, Martyn, George, Michael W
Format: Artikel
Sprache:eng
Schlagworte:
oxidation
photochemistry
singlet oxygen
supercritical fluids
sustainable chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:High pressure under the spotlight: A new milliliter-scale reactor is developed for using supercritical CO₂ to perform continuous photo-oxidation reactions. Changing from a traditional microliter-scale batch reaction to 8 hours of reaction using the new reactor gives a 3000-fold scale-up of the oxidation of α-terpinene (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200901731