Contemplation on spark sensitivity of certain nitramine type explosives

Spark sensitivity of explosives is an important subject. Presently, some correlations are sought between the spark sensitivity and certain molecular orbital characteristics of some nitramine type explosives. For that purpose certain semi-empirical and DFT calculations have been carried out. Investig...

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Veröffentlicht in:	Journal of hazardous materials 2009-09, Vol.169 (1), p.454-459
1. Verfasser:	Turker, L
Format:	Artikel
Sprache:	eng
Schlagworte:	Aniline Compounds - chemistry Anions Applied sciences Electrons Exact sciences and technology Explosive Agents - chemistry Explosives Fires Models, Molecular Nitramines Nitro compounds Nitrobenzenes - chemistry Pollution Spark sensitivity Static Electricity
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Spark sensitivity of explosives is an important subject. Presently, some correlations are sought between the spark sensitivity and certain molecular orbital characteristics of some nitramine type explosives. For that purpose certain semi-empirical and DFT calculations have been carried out. Investigations have revealed that the nitramines considered undergo decomposition in the electric field mainly via their anionic states.
ISSN:	0304-3894 1873-3336
DOI:	10.1016/j.jhazmat.2009.03.117