Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol esters via rearrangement of Fischer chromium chloro-carbenes using microwave irradiation

Functionalized (Z,E)-1-halo-1,3-dienol esters are synthesized in a highly stereoselective manner via CrCl2-mediated rearrangement of allylic trihalomethylcarbinol esters induced by microwave irradiation.

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Bibliographische Detailangaben
Veröffentlicht in:	Organic & biomolecular chemistry 2009-01, Vol.7 (9), p.1771-1774
Hauptverfasser:	Kashinath, Dhurke, Mioskowski, Charles, Falck, J R, Goli, Mohan, Meunier, Stéphane, Baati, Rachid, Wagner, Alain
Format:	Artikel
Sprache:	eng
Schlagworte:	Chlorides - chemistry Chromium Compounds - chemistry Esters - chemical synthesis Esters - chemistry Methane - analogs & derivatives Methane - chemistry Microwaves Molecular Structure Stereoisomerism
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Beschreibung
Zusammenfassung:	Functionalized (Z,E)-1-halo-1,3-dienol esters are synthesized in a highly stereoselective manner via CrCl2-mediated rearrangement of allylic trihalomethylcarbinol esters induced by microwave irradiation.
ISSN:	1477-0520 1477-0539
DOI:	10.1039/b903244b