Asymmetric Friedel-Crafts reaction of N-heterocycles and nitroalkenes catalyzed by imidazoline-aminophenol-Cu complex

Asymmetric Friedel-Crafts reaction of N-heterocycles and nitroalkenes catalyzed by imidazoline-aminophenol-Cu complex

Catalytic asymmetric Friedel-Crafts reaction of pyrrole with nitroalkenes was smoothly catalyzed by newly synthesized nitro-substituted imidazoline-aminophenol (1b)-Cu complex to give the adduct with up to 92% ee.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (22), p.3285-3287
Hauptverfasser: Yokoyama, Naota, Arai, Takayoshi
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemistry
Catalysis
Heterocyclic Compounds - chemistry
Imidazolines - chemistry
Organometallic Compounds - chemistry
Pyrroles - chemistry
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Beschreibung
Zusammenfassung:Catalytic asymmetric Friedel-Crafts reaction of pyrrole with nitroalkenes was smoothly catalyzed by newly synthesized nitro-substituted imidazoline-aminophenol (1b)-Cu complex to give the adduct with up to 92% ee.
ISSN:1359-7345
1364-548X
DOI:10.1039/b904275j