Microwave-Assisted Regioselective Addition of P(O)−H Bonds to Alkenes without Added Solvent or Catalyst

Microwave-Assisted Regioselective Addition of P(O)−H Bonds to Alkenes without Added Solvent or Catalyst

The addition of P(O)−H bonds to alkenes has been accomplished using microwave irradiation in the absence of added solvent and catalyst. In addition to single addition reactions, tandem hydrophosphinylation reactions with alkynes afforded unsymmetrical species such as phosphine oxide − phosphinates....

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Veröffentlicht in:Organic letters 2005-03, Vol.7 (5), p.851-853
Hauptverfasser: Stockland, Robert A, Taylor, Ross I, Thompson, Laura E, Patel, Priti B
Format: Artikel
Sprache:eng
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Zusammenfassung:The addition of P(O)−H bonds to alkenes has been accomplished using microwave irradiation in the absence of added solvent and catalyst. In addition to single addition reactions, tandem hydrophosphinylation reactions with alkynes afforded unsymmetrical species such as phosphine oxide − phosphinates.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol0474047