[MoO2Cl2] as catalyst for hydrosilylation of aldehydes and ketones

[MoO2Cl2] as catalyst for hydrosilylation of aldehydes and ketones

The high valent molybdenum-dioxo complex [MoO2Cl2] catalyzes the addition of dimethylphenylsilane to aldehydes and ketones to afford the corresponding dimethylphenylsilyl ethers in quantitative yield.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-01 (2), p.213-214
Hauptverfasser: Fernandes, Ana C, Fernandes, Ricardo, Romao, Carlos C, Royo, Beatriz
Format: Artikel
Sprache:eng
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Zusammenfassung:The high valent molybdenum-dioxo complex [MoO2Cl2] catalyzes the addition of dimethylphenylsilane to aldehydes and ketones to afford the corresponding dimethylphenylsilyl ethers in quantitative yield.
ISSN:1359-7345
1364-548X
DOI:10.1039/b414145h