Trifunctional N,N,O-Terdentate Amido/Pyridyl Carboxylate Ligated Pd(II) Complexes for Heck and Suzuki Reactions

Trifunctional N,N,O-terdentate amido/pyridyl carboxylate Pd(II) complexes were highly active and stable phosphine-free catalysts for Heck and room-temperature Suzuki reactions with high turnover numbers up to ca. 104.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of organic chemistry 2009-07, Vol.74 (13), p.4882-4885
Hauptverfasser:	Kantam, M. Lakshmi, Srinivas, P, Yadav, Jagjit, Likhar, Pravin R, Bhargava, Suresh
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Ligands Magnetic Resonance Spectroscopy Molecular Structure Noncondensed benzenic compounds Organic chemistry Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Palladium - chemistry Preparations and properties Structure-Activity Relationship Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Beschreibung
Zusammenfassung:	Trifunctional N,N,O-terdentate amido/pyridyl carboxylate Pd(II) complexes were highly active and stable phosphine-free catalysts for Heck and room-temperature Suzuki reactions with high turnover numbers up to ca. 104.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo900361c