Ionic radii for Group 1 halide crystals and ion-pairs
Internuclear separations calculated from empirical soft-sphere radii for seventeen crystalline Group 1 halides with rock-salt structures and from empirical hovering-sphere radii for fourteen gaseous Group 1 halide ion-pairs agree well with experimental measurements. Two lithium and four fluoride ion...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2005-02 (4), p.702-705 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Internuclear separations calculated from empirical soft-sphere radii for seventeen crystalline Group 1 halides with rock-salt structures and from empirical hovering-sphere radii for fourteen gaseous Group 1 halide ion-pairs agree well with experimental measurements. Two lithium and four fluoride ion-pairs appear to be anomalous. Soft-sphere ionic radii are compared with atomic radii of noble gases. |
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| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/b410521b |