Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate

Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate

Samarium chloride and borohydride complexes of the diamide-diamine ligands (2-C5H4N)CH2N(CH2CH2NR)2(R = SiMe3 or mesityl) are described; the borohydride compounds are the first polydentate amide-supported single component lanthanide catalysts for the controlled polymerisation of polar monomers, and...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2005-02 (3), p.421-423
Hauptverfasser: Bonnet, Fanny, Hillier, Anna C, Collins, Anna, Dubberley, Stuart R, Mountford, Philip
Format: Artikel
Sprache:eng
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Zusammenfassung:Samarium chloride and borohydride complexes of the diamide-diamine ligands (2-C5H4N)CH2N(CH2CH2NR)2(R = SiMe3 or mesityl) are described; the borohydride compounds are the first polydentate amide-supported single component lanthanide catalysts for the controlled polymerisation of polar monomers, and also represent the first lanthanide borohydride complex for the polymerisation of methyl methacrylate.
ISSN:1477-9226
1477-9234
DOI:10.1039/b417279p