A Two-Step Reaction Sequence for the Syntheses of Tetrahydronaphthalenes

A Two-Step Reaction Sequence for the Syntheses of Tetrahydronaphthalenes

A cobalt(I)-catalyzed Diels−Alder reaction of a boron-functionalized enyne is the key step in a two-step reaction cascade interconnecting four simple starting materials to obtain polycyclic multifunctionalized products in good yields and with a very high degree of diastereoselectivity.

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Veröffentlicht in:Organic letters 2005-01, Vol.7 (2), p.251-253
Hauptverfasser: Hilt, Gerhard, Lüers, Steffen, Smolko, Konstantin I
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes - chemistry
Boron Compounds - chemistry
Cobalt - chemistry
Molecular Structure
Stereoisomerism
Tetrahydronaphthalenes - chemical synthesis
Tetrahydronaphthalenes - chemistry
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Zusammenfassung:A cobalt(I)-catalyzed Diels−Alder reaction of a boron-functionalized enyne is the key step in a two-step reaction cascade interconnecting four simple starting materials to obtain polycyclic multifunctionalized products in good yields and with a very high degree of diastereoselectivity.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol0477879