Synthesis of Structurally Diverse and Defined Bivalent Mannosides on Saccharide Scaffolding

Synthesis of Structurally Diverse and Defined Bivalent Mannosides on Saccharide Scaffolding

The synthesis of bivalent mannosides by the grafting of α-d-mannopyranoside onto monosaccharide acceptors and conjugation to terephthalic acid or phenylenediamine is described. Computational methods were used to predict accessible orientations and distances between the mannose units.

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Veröffentlicht in:Organic letters 2005-01, Vol.7 (2), p.211-214
Hauptverfasser: Tosin, Manuela, Gouin, Sebastien G, Murphy, Paul V
Format: Artikel
Sprache:eng
Schlagworte:
Carbohydrate Sequence
Computer Simulation
Mannosides - chemical synthesis
Mannosides - chemistry
Molecular Sequence Data
Molecular Structure
Monosaccharides - chemistry
Phenylenediamines - chemistry
Phthalic Acids - chemistry
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Beschreibung
Zusammenfassung:The synthesis of bivalent mannosides by the grafting of α-d-mannopyranoside onto monosaccharide acceptors and conjugation to terephthalic acid or phenylenediamine is described. Computational methods were used to predict accessible orientations and distances between the mannose units.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol047841l