Nitrogenous Educts through Oxidative Amidation of Phenols:  The Bimolecular Reaction

The elusive oxidative amidation of phenols to 4-aza-substituted dienones in the bimolecular mode may be achieved by treatment with iodobenzene diacetate (“DIB”) in a mixture of hexafluoro-2-propanol and acetonitrile.

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Veröffentlicht in:Organic letters 2005-01, Vol.7 (2), p.175-177
Hauptverfasser: Canesi, Sylvain, Bouchu, Denis, Ciufolini, Marco A
Format: Artikel
Sprache:eng
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Zusammenfassung:The elusive oxidative amidation of phenols to 4-aza-substituted dienones in the bimolecular mode may be achieved by treatment with iodobenzene diacetate (“DIB”) in a mixture of hexafluoro-2-propanol and acetonitrile.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol048094v