Bis(acesulfamato)tetraaquacobalt(II)

Bis(acesulfamato)tetraaquacobalt(II)

The crystal structure of the first acesulfame-metal complex, namely tetraaquabis[6-methyl-1,2,3-oxathiazin-4(3H)-onato 2,2-dioxide-kappaN]cobalt(II), [Co(C4H4NO4S)2(H2O)4], is reported. The Co(II) ion resides on a twofold axis and is coordinated by four aqua ligands defining the basal plane and by t...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2005-01, Vol.61 (Pt 1), p.m1-m3
Hauptverfasser: ICBUDAK, Hasan, BULUT, Ahmet, CETIN, Naziye, KAZAK, Canan
Format: Artikel
Sprache:eng
Schlagworte:
Cobalt - chemistry
Condensed matter: structure, mechanical and thermal properties
Crystalline state (including molecular motions in solids)
Crystallography, X-Ray
Exact sciences and technology
Hydrogen Bonding
Molecular Structure
Organometallic Compounds - chemistry
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Theory of crystal structure, crystal symmetry
calculations and modeling
Thiazines - chemistry
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Zusammenfassung:The crystal structure of the first acesulfame-metal complex, namely tetraaquabis[6-methyl-1,2,3-oxathiazin-4(3H)-onato 2,2-dioxide-kappaN]cobalt(II), [Co(C4H4NO4S)2(H2O)4], is reported. The Co(II) ion resides on a twofold axis and is coordinated by four aqua ligands defining the basal plane and by two monodentate acesulfamate ligands, via their ring N atoms, in the axial positions. Two intra- and three intermolecular hydrogen-bonding interactions stabilize the crystal structure and form an infinite three-dimensional lattice.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270104028574