Structural and Spectroscopic Characterization of (μ-Hydroxo or μ-Oxo)(μ-peroxo)diiron(III) Complexes:  Models for Peroxo Intermediates of Non-Heme Diiron Proteins

Structural and Spectroscopic Characterization of (μ-Hydroxo or μ-Oxo)(μ-peroxo)diiron(III) Complexes:  Models for Peroxo Intermediates of Non-Heme Diiron Proteins

(μ-Hydroxo or oxo)(μ-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe2(μ-OH or μ-O)(μ-O2)(L)2] n + were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 2005-01, Vol.127 (3), p.826-827
Hauptverfasser: Zhang, Xi, Furutachi, Hideki, Fujinami, Shuhei, Nagatomo, Shigenori, Maeda, Yonezo, Watanabe, Yoshihito, Kitagawa, Teizo, Suzuki, Masatatsu
Format: Artikel
Sprache:eng
Schlagworte:
Bioinorganic chemistry
Biological and medical sciences
Biomimetic Materials - chemistry
Chemistry
Electronic structure
Exact sciences and technology
Ferric Compounds - chemistry
Fundamental and applied biological sciences. Psychology
Inorganic chemistry and origins of life
Molecular biophysics
Nonheme Iron Proteins - chemistry
Spectroscopy, Mossbauer
Spectrum Analysis, Raman
Structure in molecular biology
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:(μ-Hydroxo or oxo)(μ-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe2(μ-OH or μ-O)(μ-O2)(L)2] n + were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja045594a