Undecanuclear mixed-valence 3d-4f bimetallic clusters

Undecanuclear mixed-valence 3d-4f bimetallic clusters

Two undecanuclear 3d-4f clusters with the general formula {Mn(III)(4)Mn(IV)Ln(III)(6)}, where Ln = Gd or Tb, were synthesized, with both showing large spin ground states, and the Tb species acting as a single molecule magnet.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (24), p.3568-3570
Hauptverfasser: Shiga, Takuya, Onuki, Tatsuya, Matsumoto, Takuto, Nojiri, Hiroyuki, Newton, Graham N, Hoshino, Norihisa, Oshio, Hiroki
Format: Artikel
Sprache:eng
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Zusammenfassung:Two undecanuclear 3d-4f clusters with the general formula {Mn(III)(4)Mn(IV)Ln(III)(6)}, where Ln = Gd or Tb, were synthesized, with both showing large spin ground states, and the Tb species acting as a single molecule magnet.
ISSN:1359-7345
1364-548X
DOI:10.1039/b905480d