The role of metals in dioxin formation from combustion of newspapers and polyvinyl chloride in an incinerator
Newspapers impregnated with NaCl mixed with various chloride metals (CuCl 2, MgCl 2, MnCl 2, FeCl 3, NiCl 2, and CoCl 2) and electric wire coated with polyvinyl chloride (PVC) were combusted in a well-controlled incinerator. Exhaust gas samples collected at the outlet of the incinerator were analyze...
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Veröffentlicht in: | Chemosphere (Oxford) 2005-02, Vol.58 (7), p.891-896 |
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creator | Yasuhara, Akio Tanaka, Yuuka Katami, Takeo Shibamoto, Takayuki |
description | Newspapers impregnated with NaCl mixed with various chloride metals (CuCl
2, MgCl
2, MnCl
2, FeCl
3, NiCl
2, and CoCl
2) and electric wire coated with polyvinyl chloride (PVC) were combusted in a well-controlled incinerator. Exhaust gas samples collected at the outlet of the incinerator were analyzed for dioxins (PCDDs, PCDFs, and coplanar PCBs) by gas chromatography/mass spectrometry. The amount of total dioxins formed from newspaper samples ranged from 34.2
ng/g (with NaCl
+
CoCl
2) to 67.0
ng/g (with NaCl
+
CuCl
2). PCDFs composed 88–94% of the total dioxins formed in the exhaust gases. The highest levels of PCDF isomers obtained were Cl
3-CDF from the sample with NaCl
+
CuCl
2 (14.8
ng/g), Cl
2-CDF from the sample with NaCl
+
MgCl
2 (12.3
ng/g), and Cl
1-CDF from samples with NaCl
+
MnCl
2 (12.6
ng/g), with NaCl
+
FeCl
3 (11.8
ng/g), and with NaCl
+
NiCl
2 (13.3
ng/g), and with NaCl
+
CoCl
2 (8.62
ng/g). The total of Cl
4–8-CDDs comprised 76–88% of the total Cl
1–8-CDDs. In particular, Cl
7-CDDs had the highest levels except for the sample with NaCl
+
NiCl
2. Total dioxins formed from samples of electric wire coated with PVC and PVC alone were 38.3
ng/g and 112
ng/g, respectively, suggesting that the presence of copper reduced dioxin formation. |
doi_str_mv | 10.1016/j.chemosphere.2004.08.104 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_67355316</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0045653504007969</els_id><sourcerecordid>19806920</sourcerecordid><originalsourceid>FETCH-LOGICAL-c533t-f16fb1ab7c90b8bab77ca5134aeb7329a52f13b19e80a8585475dca83672147c3</originalsourceid><addsrcrecordid>eNqNkU1P3DAQhq2qqCy0f6Eyh_aWxR-xYx-rFQUkJC5wthxnovUqjoOdBfbf4-2uRG9w8czofWbGmhehC0qWlFB5uVm6NYSYpzUkWDJC6iVRRaq_oAVVja4o0-orWhRBVFJwcYrOct4QUpqF_oZOqZBcM0kWKDysAac4AI49DjDbIWM_4s7H1xL6mIKdfSxZigG7GNpt_lcXeoSXPNkJUsZ27PAUh92zH3cDdushJt_BfpAdy-v8CMnOMX1HJ33ZAD-O8Rw9_r16WN1Ud_fXt6s_d5UTnM9VT2XfUts2TpNWtSVpnBWU1xbahjNtBespb6kGRawSStSN6JxVXDaM1o3j5-j3Ye6U4tMW8myCzw6GwY4Qt9nIhgvBqfwQZFrXhDD1IUi1IlIzUkB9AF2KOSfozZR8sGlnKDF798zG_Oee2btniCpSXXp_Hpds2wDde-fRrgL8OgI2Ozv0yZbb5ndOClaupAu3OnBQjvzsIZnsPIwOOp_AzaaL_hPfeQOon7-7</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>19806920</pqid></control><display><type>article</type><title>The role of metals in dioxin formation from combustion of newspapers and polyvinyl chloride in an incinerator</title><source>MEDLINE</source><source>Access via ScienceDirect (Elsevier)</source><creator>Yasuhara, Akio ; Tanaka, Yuuka ; Katami, Takeo ; Shibamoto, Takayuki</creator><creatorcontrib>Yasuhara, Akio ; Tanaka, Yuuka ; Katami, Takeo ; Shibamoto, Takayuki</creatorcontrib><description>Newspapers impregnated with NaCl mixed with various chloride metals (CuCl
2, MgCl
2, MnCl
2, FeCl
3, NiCl
2, and CoCl
2) and electric wire coated with polyvinyl chloride (PVC) were combusted in a well-controlled incinerator. Exhaust gas samples collected at the outlet of the incinerator were analyzed for dioxins (PCDDs, PCDFs, and coplanar PCBs) by gas chromatography/mass spectrometry. The amount of total dioxins formed from newspaper samples ranged from 34.2
ng/g (with NaCl
+
CoCl
2) to 67.0
ng/g (with NaCl
+
CuCl
2). PCDFs composed 88–94% of the total dioxins formed in the exhaust gases. The highest levels of PCDF isomers obtained were Cl
3-CDF from the sample with NaCl
+
CuCl
2 (14.8
ng/g), Cl
2-CDF from the sample with NaCl
+
MgCl
2 (12.3
ng/g), and Cl
1-CDF from samples with NaCl
+
MnCl
2 (12.6
ng/g), with NaCl
+
FeCl
3 (11.8
ng/g), and with NaCl
+
NiCl
2 (13.3
ng/g), and with NaCl
+
CoCl
2 (8.62
ng/g). The total of Cl
4–8-CDDs comprised 76–88% of the total Cl
1–8-CDDs. In particular, Cl
7-CDDs had the highest levels except for the sample with NaCl
+
NiCl
2. Total dioxins formed from samples of electric wire coated with PVC and PVC alone were 38.3
ng/g and 112
ng/g, respectively, suggesting that the presence of copper reduced dioxin formation.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/j.chemosphere.2004.08.104</identifier><identifier>PMID: 15639260</identifier><identifier>CODEN: CMSHAF</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Atmospheric pollution ; Combustion and energy production ; Dioxins - analysis ; Dioxins - chemistry ; Electricity ; Exact sciences and technology ; Incineration ; Isomerism ; Metals ; Newspapers as Topic ; Pollution ; Pollution sources. Measurement results ; Polyvinyl Chloride - chemistry</subject><ispartof>Chemosphere (Oxford), 2005-02, Vol.58 (7), p.891-896</ispartof><rights>2004 Elsevier Ltd</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c533t-f16fb1ab7c90b8bab77ca5134aeb7329a52f13b19e80a8585475dca83672147c3</citedby><cites>FETCH-LOGICAL-c533t-f16fb1ab7c90b8bab77ca5134aeb7329a52f13b19e80a8585475dca83672147c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.chemosphere.2004.08.104$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16521349$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15639260$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yasuhara, Akio</creatorcontrib><creatorcontrib>Tanaka, Yuuka</creatorcontrib><creatorcontrib>Katami, Takeo</creatorcontrib><creatorcontrib>Shibamoto, Takayuki</creatorcontrib><title>The role of metals in dioxin formation from combustion of newspapers and polyvinyl chloride in an incinerator</title><title>Chemosphere (Oxford)</title><addtitle>Chemosphere</addtitle><description>Newspapers impregnated with NaCl mixed with various chloride metals (CuCl
2, MgCl
2, MnCl
2, FeCl
3, NiCl
2, and CoCl
2) and electric wire coated with polyvinyl chloride (PVC) were combusted in a well-controlled incinerator. Exhaust gas samples collected at the outlet of the incinerator were analyzed for dioxins (PCDDs, PCDFs, and coplanar PCBs) by gas chromatography/mass spectrometry. The amount of total dioxins formed from newspaper samples ranged from 34.2
ng/g (with NaCl
+
CoCl
2) to 67.0
ng/g (with NaCl
+
CuCl
2). PCDFs composed 88–94% of the total dioxins formed in the exhaust gases. The highest levels of PCDF isomers obtained were Cl
3-CDF from the sample with NaCl
+
CuCl
2 (14.8
ng/g), Cl
2-CDF from the sample with NaCl
+
MgCl
2 (12.3
ng/g), and Cl
1-CDF from samples with NaCl
+
MnCl
2 (12.6
ng/g), with NaCl
+
FeCl
3 (11.8
ng/g), and with NaCl
+
NiCl
2 (13.3
ng/g), and with NaCl
+
CoCl
2 (8.62
ng/g). The total of Cl
4–8-CDDs comprised 76–88% of the total Cl
1–8-CDDs. In particular, Cl
7-CDDs had the highest levels except for the sample with NaCl
+
NiCl
2. Total dioxins formed from samples of electric wire coated with PVC and PVC alone were 38.3
ng/g and 112
ng/g, respectively, suggesting that the presence of copper reduced dioxin formation.</description><subject>Applied sciences</subject><subject>Atmospheric pollution</subject><subject>Combustion and energy production</subject><subject>Dioxins - analysis</subject><subject>Dioxins - chemistry</subject><subject>Electricity</subject><subject>Exact sciences and technology</subject><subject>Incineration</subject><subject>Isomerism</subject><subject>Metals</subject><subject>Newspapers as Topic</subject><subject>Pollution</subject><subject>Pollution sources. Measurement results</subject><subject>Polyvinyl Chloride - chemistry</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkU1P3DAQhq2qqCy0f6Eyh_aWxR-xYx-rFQUkJC5wthxnovUqjoOdBfbf4-2uRG9w8czofWbGmhehC0qWlFB5uVm6NYSYpzUkWDJC6iVRRaq_oAVVja4o0-orWhRBVFJwcYrOct4QUpqF_oZOqZBcM0kWKDysAac4AI49DjDbIWM_4s7H1xL6mIKdfSxZigG7GNpt_lcXeoSXPNkJUsZ27PAUh92zH3cDdushJt_BfpAdy-v8CMnOMX1HJ33ZAD-O8Rw9_r16WN1Ud_fXt6s_d5UTnM9VT2XfUts2TpNWtSVpnBWU1xbahjNtBespb6kGRawSStSN6JxVXDaM1o3j5-j3Ye6U4tMW8myCzw6GwY4Qt9nIhgvBqfwQZFrXhDD1IUi1IlIzUkB9AF2KOSfozZR8sGlnKDF798zG_Oee2btniCpSXXp_Hpds2wDde-fRrgL8OgI2Ozv0yZbb5ndOClaupAu3OnBQjvzsIZnsPIwOOp_AzaaL_hPfeQOon7-7</recordid><startdate>20050201</startdate><enddate>20050201</enddate><creator>Yasuhara, Akio</creator><creator>Tanaka, Yuuka</creator><creator>Katami, Takeo</creator><creator>Shibamoto, Takayuki</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TV</scope><scope>7U7</scope><scope>C1K</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope></search><sort><creationdate>20050201</creationdate><title>The role of metals in dioxin formation from combustion of newspapers and polyvinyl chloride in an incinerator</title><author>Yasuhara, Akio ; Tanaka, Yuuka ; Katami, Takeo ; Shibamoto, Takayuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c533t-f16fb1ab7c90b8bab77ca5134aeb7329a52f13b19e80a8585475dca83672147c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>Atmospheric pollution</topic><topic>Combustion and energy production</topic><topic>Dioxins - analysis</topic><topic>Dioxins - chemistry</topic><topic>Electricity</topic><topic>Exact sciences and technology</topic><topic>Incineration</topic><topic>Isomerism</topic><topic>Metals</topic><topic>Newspapers as Topic</topic><topic>Pollution</topic><topic>Pollution sources. Measurement results</topic><topic>Polyvinyl Chloride - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yasuhara, Akio</creatorcontrib><creatorcontrib>Tanaka, Yuuka</creatorcontrib><creatorcontrib>Katami, Takeo</creatorcontrib><creatorcontrib>Shibamoto, Takayuki</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yasuhara, Akio</au><au>Tanaka, Yuuka</au><au>Katami, Takeo</au><au>Shibamoto, Takayuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The role of metals in dioxin formation from combustion of newspapers and polyvinyl chloride in an incinerator</atitle><jtitle>Chemosphere (Oxford)</jtitle><addtitle>Chemosphere</addtitle><date>2005-02-01</date><risdate>2005</risdate><volume>58</volume><issue>7</issue><spage>891</spage><epage>896</epage><pages>891-896</pages><issn>0045-6535</issn><eissn>1879-1298</eissn><coden>CMSHAF</coden><abstract>Newspapers impregnated with NaCl mixed with various chloride metals (CuCl
2, MgCl
2, MnCl
2, FeCl
3, NiCl
2, and CoCl
2) and electric wire coated with polyvinyl chloride (PVC) were combusted in a well-controlled incinerator. Exhaust gas samples collected at the outlet of the incinerator were analyzed for dioxins (PCDDs, PCDFs, and coplanar PCBs) by gas chromatography/mass spectrometry. The amount of total dioxins formed from newspaper samples ranged from 34.2
ng/g (with NaCl
+
CoCl
2) to 67.0
ng/g (with NaCl
+
CuCl
2). PCDFs composed 88–94% of the total dioxins formed in the exhaust gases. The highest levels of PCDF isomers obtained were Cl
3-CDF from the sample with NaCl
+
CuCl
2 (14.8
ng/g), Cl
2-CDF from the sample with NaCl
+
MgCl
2 (12.3
ng/g), and Cl
1-CDF from samples with NaCl
+
MnCl
2 (12.6
ng/g), with NaCl
+
FeCl
3 (11.8
ng/g), and with NaCl
+
NiCl
2 (13.3
ng/g), and with NaCl
+
CoCl
2 (8.62
ng/g). The total of Cl
4–8-CDDs comprised 76–88% of the total Cl
1–8-CDDs. In particular, Cl
7-CDDs had the highest levels except for the sample with NaCl
+
NiCl
2. Total dioxins formed from samples of electric wire coated with PVC and PVC alone were 38.3
ng/g and 112
ng/g, respectively, suggesting that the presence of copper reduced dioxin formation.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><pmid>15639260</pmid><doi>10.1016/j.chemosphere.2004.08.104</doi><tpages>6</tpages></addata></record> |
fulltext | fulltext |
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language | eng |
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source | MEDLINE; Access via ScienceDirect (Elsevier) |
subjects | Applied sciences Atmospheric pollution Combustion and energy production Dioxins - analysis Dioxins - chemistry Electricity Exact sciences and technology Incineration Isomerism Metals Newspapers as Topic Pollution Pollution sources. Measurement results Polyvinyl Chloride - chemistry |
title | The role of metals in dioxin formation from combustion of newspapers and polyvinyl chloride in an incinerator |
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