Mechanistic insights into a copper-disulfide interaction in oxidation of imines by disulfides

Mechanistic insights into a copper-disulfide interaction in oxidation of imines by disulfides

The concept of using disulfides as an oxidant for Cu(i) is introduced as part of a Cu-catalyzed process leading to the formation of benzothiazole from an iminodisulfide under an inert atmosphere.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (23), p.3463-3465
Hauptverfasser: Srogl, Jiri, Hývl, Jakub, Révész, Agnes, Schröder, Detlef
Format: Artikel
Sprache:eng
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Zusammenfassung:The concept of using disulfides as an oxidant for Cu(i) is introduced as part of a Cu-catalyzed process leading to the formation of benzothiazole from an iminodisulfide under an inert atmosphere.
ISSN:1359-7345
1364-548X
DOI:10.1039/b904403e