Structural Tracking of a Bimolecular Reaction in Solution by Time‐Resolved X‐Ray Scattering

Molecular movies: Time‐resolved X‐ray scattering provides direct structural information on an electronically excited complex while it is formed in the bimolecular reaction between excited octahydrogen[tetrakis‐μ‐diphosphito‐1κP:2κP′‐diplatinate](4‐) (PtPOP*) and thallium ions. In the exciplex one th...

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Veröffentlicht in:	Angewandte Chemie International Edition 2009-05, Vol.48 (23), p.4180-4184
Hauptverfasser:	Haldrup, Kristoffer, Christensen, Morten, Cammarata, Marco, Kong, Qingyu, Wulff, Michael, Mariager, Simon O., Bechgaard, Klaus, Feidenhans'l, Robert, Harrit, Niels, Nielsen, Martin M.
Format:	Artikel
Sprache:	eng
Schlagworte:	exciplexes photochemistry platinum X‐ray scattering
Online-Zugang:	Volltext
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Zusammenfassung:	Molecular movies: Time‐resolved X‐ray scattering provides direct structural information on an electronically excited complex while it is formed in the bimolecular reaction between excited octahydrogen[tetrakis‐μ‐diphosphito‐1κP:2κP′‐diplatinate](4‐) (PtPOP) and thallium ions. In the exciplex one thallium(I) and two platinum(II) ions are found to be collinear. Molecular movies: Time‐resolved X‐ray scattering provides direct structural information on an electronically excited complex while it is formed in the bimolecular reaction between excited octahydrogen[tetrakis‐μ‐diphosphito‐1κP:2κP′‐diplatinate](4‐) (PtPOP) and thallium ions. In the exciplex one thallium(I) and two platinum(II) ions are found to be collinear.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200900741