Two-directional cross-metathesis

Two-directional cross-metathesis

Two-directional cross-metathesis of a range of alpha,omega dienes with a variety of electron deficient alkenes has been accomplished. It was found that the process is quite general and gives complete selectivity for the E,E-dienes, making this a very useful and high yielding protocol for two-directi...

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Veröffentlicht in:Organic & biomolecular chemistry 2009-01, Vol.7 (11), p.2274-2277
Hauptverfasser: Newton, Annabella F, Roe, Stephen J, Legeay, Jean-Christophe, Aggarwal, Pooja, Gignoux, Camille, Birch, Nicola J, Nixon, Robert, Alcaraz, Marie-Lyne, Stockman, Robert A
Format: Artikel
Sprache:eng
Schlagworte:
Alkadienes - chemical synthesis
Alkadienes - chemistry
Alkenes - chemical synthesis
Alkenes - chemistry
Catalysis
Electrons
Molecular Structure
Stereoisomerism
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Zusammenfassung:Two-directional cross-metathesis of a range of alpha,omega dienes with a variety of electron deficient alkenes has been accomplished. It was found that the process is quite general and gives complete selectivity for the E,E-dienes, making this a very useful and high yielding protocol for two-directional chain elongation.
ISSN:1477-0520
1477-0539
DOI:10.1039/b907720k