Self-assembly of a bis(adeninyl)-Cu(I) complex: a cationic nucleobase duplex mimic

The tetrahedral bis(adeninyl)-Cu(I) complex, , self-associates in polar solvent through complementary hydrogen-bonding interactions and appears to mimic the natural assembly of duplex DNA.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2009-01 (20), p.2833-2835
Hauptverfasser:	Galindo, Miguel A, Amantia, David, Clegg, William, Harrington, Ross W, Eyre, Richard J, Goss, Jonathon P, Briddon, Patrick R, McFarlane, William, Houlton, Andrew
Format:	Artikel
Sprache:	eng
Schlagworte:	Adenine - chemical synthesis Adenine - chemistry Biomimetics Cations - chemical synthesis Cations - chemistry Copper - chemistry Dimerization Dimethyl Sulfoxide - chemistry DNA - chemistry Hydrogen Bonding Models, Molecular Molecular Structure Nucleic Acid Conformation
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Beschreibung
Zusammenfassung:	The tetrahedral bis(adeninyl)-Cu(I) complex, , self-associates in polar solvent through complementary hydrogen-bonding interactions and appears to mimic the natural assembly of duplex DNA.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b817329j