Copper(0)-Induced Deselenative Insertion of N,N-Disubstituted Selenoamides into Acetylenic C−H Bond Leading to Propargylamines

Copper(0)-Induced Deselenative Insertion of N,N-Disubstituted Selenoamides into Acetylenic C−H Bond Leading to Propargylamines

Upon heating at 110 °C in the presence of copper(0) powder, terminal acetylenes undergo a novel deselenative C−H bond insertion reaction of N,N-disubstituted selenoamides, affording the corresponding propargylamines in good to excellent yields, selectively.

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Veröffentlicht in:Organic letters 2009-05, Vol.11 (10), p.2045-2048
Hauptverfasser: Mitamura, Takenori, Ogawa, Akiya
Format: Artikel
Sprache:eng
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Zusammenfassung:Upon heating at 110 °C in the presence of copper(0) powder, terminal acetylenes undergo a novel deselenative C−H bond insertion reaction of N,N-disubstituted selenoamides, affording the corresponding propargylamines in good to excellent yields, selectively.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol9001976