Aerobic oxidation of alkenes mediated by porphyrin rhodium(III) complexes in water

Selective oxidation of alkenes in water to ketones using molecular oxygen as the oxidant is mediated by rhodium porphyrin complexes through observed beta-hydroxy alkyl complexes.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2009-01 (19), p.3661-3663
Hauptverfasser: Zhang, Jiadi, Li, Shan, Fu, Xuefeng, Wayland, Bradford B
Format: Artikel
Sprache:eng
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Zusammenfassung:Selective oxidation of alkenes in water to ketones using molecular oxygen as the oxidant is mediated by rhodium porphyrin complexes through observed beta-hydroxy alkyl complexes.
ISSN:1477-9226
1477-9234
DOI:10.1039/b904414k