Effect of TMEDA on Iron-Catalyzed Coupling Reactions of ArMgX with Alkyl Halides

Effect of TMEDA on Iron-Catalyzed Coupling Reactions of ArMgX with Alkyl Halides

A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

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Veröffentlicht in:Journal of the American Chemical Society 2009-05, Vol.131 (17), p.6078-6079
Hauptverfasser: Noda, Daisuke, Sunada, Yusuke, Hatakeyama, Takuji, Nakamura, Masaharu, Nagashima, Hideo
Format: Artikel
Sprache:eng
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Zusammenfassung:A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja901262g