Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80

Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80

The X-ray crystal structure of Gd(3)N@C(80).Ni(II)(OEP).1.5(benzene) shows that the Gd(3)N unit within the I(h) C(80) cage is pyramidal, whereas Sc(3)N@C(80), Sc(3)N@C(78), Sc(3)N@C(68), Lu(3)N@C(80) and Sc(2)ErN@C(80) have planar M(3)N units.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-12 (24), p.2814-2815
Hauptverfasser: Stevenson, Steven, Phillips, J Paige, Reid, Jon E, Olmstead, Marilyn M, Rath, Sankar Prasad, Balch, Alan L
Format: Artikel
Sprache:eng
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Zusammenfassung:The X-ray crystal structure of Gd(3)N@C(80).Ni(II)(OEP).1.5(benzene) shows that the Gd(3)N unit within the I(h) C(80) cage is pyramidal, whereas Sc(3)N@C(80), Sc(3)N@C(78), Sc(3)N@C(68), Lu(3)N@C(80) and Sc(2)ErN@C(80) have planar M(3)N units.
ISSN:1359-7345
1364-548X
DOI:10.1039/b412338g