Dinuclear Nickel(I) Dinitrogen Complex and its Reduction in Single-Electron Steps

Dinuclear Nickel(I) Dinitrogen Complex and its Reduction in Single-Electron Steps

Electron by electron: β-Diketiminato nickel(I) complex fragments are capable of activating N₂ through coordination. The resulting complex can be reduced in two single-electron steps, which further activates the N---N bond. The picture shows the structure of the singly reduced complex with μ-η¹:η¹-bo...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-01, Vol.48 (18), p.3357-3361
Hauptverfasser: Pfirrmann, Stefan, Limberg, Christian, Herwig, Christian, Stößer, Reinhard, Ziemer, Burkhard
Format: Artikel
Sprache:eng
Schlagworte:
coordination chemistry
nickel
nitrogen
nitrogen activation
β‐diketiminates
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Zusammenfassung:Electron by electron: β-Diketiminato nickel(I) complex fragments are capable of activating N₂ through coordination. The resulting complex can be reduced in two single-electron steps, which further activates the N---N bond. The picture shows the structure of the singly reduced complex with μ-η¹:η¹-bound N₂.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200805862