A new trinuclear Cu(II) complex of inositol as a hydrogelator

A new trinuclear Cu(II) complex of inositol as a hydrogelator

A trinuclear copper(II) complex with inositol and 2,2'-bipyridine forms a fibrous hydrogel at pH 12.4, the assembly of discrete trinuclear complex molecules to form the metallogel being assisted by H-bonding and inter- and intramolecular pi-stacking between the bipyridyls.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-05 (17), p.2341-2343
Hauptverfasser: Joshi, Sachin A, Kulkarni, Neelima D
Format: Artikel
Sprache:eng
Schlagworte:
Copper - chemistry
Gels - chemistry
Hydrogen - chemistry
Inositol - chemistry
Microscopy, Electron, Scanning
Molecular Structure
Spectrometry, Mass, Electrospray Ionization
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Zusammenfassung:A trinuclear copper(II) complex with inositol and 2,2'-bipyridine forms a fibrous hydrogel at pH 12.4, the assembly of discrete trinuclear complex molecules to form the metallogel being assisted by H-bonding and inter- and intramolecular pi-stacking between the bipyridyls.
ISSN:1359-7345
DOI:10.1039/b821283j