Hydride-bromide exchange at an NHC-a new route to brominated alanes and gallanes

Hydride-bromide exchange at an NHC-a new route to brominated alanes and gallanes

The reaction of [MH(3)(Quinuclidine)] (M = Al or Ga) with an air stable dibrominated N-heterocyclic carbene (NHC) affords the hydride-bromide exchange product [MBr(2)H(NHC)].

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2009-01 (16), p.2909-2911
Hauptverfasser: Alexander, Sean G, Cole, Marcus L, Furfari, Samantha K, Kloth, Marc
Format: Artikel
Sprache:eng
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Zusammenfassung:The reaction of [MH(3)(Quinuclidine)] (M = Al or Ga) with an air stable dibrominated N-heterocyclic carbene (NHC) affords the hydride-bromide exchange product [MBr(2)H(NHC)].
ISSN:1477-9226
1477-9234
DOI:10.1039/b821367d