Hydrogen Bonding in Protic Ionic Liquids: Reminiscent of Water

Similarities and differences: Far-infrared spectra of protic ionic liquids could be assigned to intermolecular bending and stretching modes of hydrogen bonds. The characteristics of the low-frequency spectra resemble those of water. Both liquids form three-dimensional network structures, but only wa...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2009-01, Vol.48 (17), p.3184-3186
Hauptverfasser:	Fumino, Koichi, Wulf, Alexander, Ludwig, Ralf
Format:	Artikel
Sprache:	eng
Schlagworte:	far‐infrared spectroscopy hydrogen bonding network structures protic ionic liquids water
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Similarities and differences: Far-infrared spectra of protic ionic liquids could be assigned to intermolecular bending and stretching modes of hydrogen bonds. The characteristics of the low-frequency spectra resemble those of water. Both liquids form three-dimensional network structures, but only water is capable of building tetrahedral configurations. EAN: ethylammonium nitrate, PAN: propylammonium nitrate, DMAN: dimethylammonium nitrate.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200806224