Bis(zinc porphyrin) Bridged by Benzo Orthocarbonates as a Conformational Switch under Regulation of DABCO and a Cu+ Ion

Bis(zinc porphyrin) Bridged by Benzo Orthocarbonates as a Conformational Switch under Regulation of DABCO and a Cu+ Ion

A tweezer-type bis(zinc porphyrin) bridged by benzo orthocarbonates was synthesized and applied as a molecular conformational switch under regulation of DABCO and a Cu+ ion. The switch property has been confirmed by 1H NMR, UV−vis spectral titration, and HR-MS spectra method.

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Veröffentlicht in:Organic letters 2009-04, Vol.11 (8), p.1781-1784
Hauptverfasser: Zhou, Zaichun, Cao, Chenzhong, Yin, Zhiqing, Liu, Qiuhua
Format: Artikel
Sprache:eng
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Zusammenfassung:A tweezer-type bis(zinc porphyrin) bridged by benzo orthocarbonates was synthesized and applied as a molecular conformational switch under regulation of DABCO and a Cu+ ion. The switch property has been confirmed by 1H NMR, UV−vis spectral titration, and HR-MS spectra method.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol802976h