An organogel system can control the stereochemical course of anthracene photodimerization

An organogel system can control the stereochemical course of anthracene photodimerization

A novel photoresponsive organogel with a binary gelator containing 2-anthracenecarboxylic acid shows a high degree of stereochemical control, resulting in head-to-head photocyclodimers exclusively together with significant enantiomeric excess induced by the chiral counterpart of the gelator.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (16), p.2100-2102
Hauptverfasser: Dawn, Arnab, Fujita, Norifumi, Haraguchi, Shuichi, Sada, Kazuki, Shinkai, Seiji
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel photoresponsive organogel with a binary gelator containing 2-anthracenecarboxylic acid shows a high degree of stereochemical control, resulting in head-to-head photocyclodimers exclusively together with significant enantiomeric excess induced by the chiral counterpart of the gelator.
ISSN:1359-7345
1364-548X
DOI:10.1039/b820565e