Diastereoselective Synthesis of Chiral Diporphyrins via Intramolecular meso−meso Oxidative Coupling

Diastereoselective syntheses of meso−meso linked diporphyrins were achieved via intramolecular chiral induction. The structures and conformations were analyzed by CD, UV, NMR, and computational calculations.

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Veröffentlicht in:	Journal of organic chemistry 2009-04, Vol.74 (8), p.3164-3167
Hauptverfasser:	Ouyang, Qin, Zhu, Yi-Zhou, Li, Yun-Chao, Wei, Hui-Bo, Zheng, Jian-Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Magnetic Resonance Spectroscopy Metalloporphyrins - chemical synthesis Metalloporphyrins - chemistry Models, Molecular Molecular Structure Organic chemistry Oxidation-Reduction Porphyrins - chemical synthesis Porphyrins - chemistry Preparations and properties Spectrophotometry, Ultraviolet Stereoisomerism Zinc - chemistry
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Beschreibung
Zusammenfassung:	Diastereoselective syntheses of meso−meso linked diporphyrins were achieved via intramolecular chiral induction. The structures and conformations were analyzed by CD, UV, NMR, and computational calculations.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo9001118