Rh(2)(II)-catalyzed synthesis of carbazoles from biaryl azides

An array of carbazoles (23 examples) can be synthesized from substituted biaryl azides at 60 degrees C using substoichiometric quantities of Rh(2)(O(2)CC(3)F(7))(4) or Rh(2)(O(2)CC(7)H(15))(4).

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of organic chemistry 2009-04, Vol.74 (8), p.3225-3228
Hauptverfasser:	Stokes, Benjamin J, Jovanović, Brankica, Dong, Huijun, Richert, Kathleen J, Riell, Ryan D, Driver, Tom G
Format:	Artikel
Sprache:	eng
Schlagworte:	Azides - chemistry Biphenyl Compounds - chemistry Carbazoles - chemical synthesis Catalysis Cyclization Magnetic Resonance Spectroscopy Molecular Structure Rhodium - chemistry Stereoisomerism Structure-Activity Relationship
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Beschreibung
Zusammenfassung:	An array of carbazoles (23 examples) can be synthesized from substituted biaryl azides at 60 degrees C using substoichiometric quantities of Rh(2)(O(2)CC(3)F(7))(4) or Rh(2)(O(2)CC(7)H(15))(4).
ISSN:	1520-6904
DOI:	10.1021/jo9002536