A Germanium(II) Cation with [1+1] Coordination

A Germanium(II) Cation with [1+1] Coordination

Breaking the molecular symmetry by protonation of germylene 1 is the key step in the synthesis of the germyliumylidene 2, which is stabilized by an intramolecular interaction with a distant imido group. Breaking the molecular symmetry by protonation of germylene 1 is the key step in the synthesis of...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry : a European journal 2009-04, Vol.15 (16), p.3945-3950
Hauptverfasser: Schäfer, Annemarie, Saak, Wolfgang, Haase, Detlev, Müller, Thomas
Format: Artikel
Sprache:eng
Schlagworte:
carbene homologues
cations
germanium
Group 14 elements
main group elements
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Breaking the molecular symmetry by protonation of germylene 1 is the key step in the synthesis of the germyliumylidene 2, which is stabilized by an intramolecular interaction with a distant imido group. Breaking the molecular symmetry by protonation of germylene 1 is the key step in the synthesis of the germyliumylidene 2, which is stabilized by an intramolecular interaction with a distant imido group.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.200900222