A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts

A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts

Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl)benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primari...

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Veröffentlicht in:Journal of the American Chemical Society 2009-04, Vol.131 (12), p.4204-4205
Hauptverfasser: Shultz, Abraham M, Farha, Omar K, Hupp, Joseph T, Nguyen, SonBinh T
Format: Artikel
Sprache:eng
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Zusammenfassung:Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl)benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja900203f